Celebrity | Brad Pitt Biggest Divorces of the Decade From Brad and Jen to Madonna and Guy, these made headlines By Evann Gastaldo Posted Dec 28, 2009 10:55 AM CST Copied Two hundred guests watched Brad Pitt and Jennifer Aniston get married in a 2000 wedding involving four bands and a choir. Just five years later, enter Angelina Jolie...and, well, you know the rest. (AP Photo/Patrick Gardin, file) See 8 more photos For better or for worse, this decade will always be remembered as the one in which that homewrecker Angelina Jolie broke up Brad Pitt and Jennifer Aniston’s marriage. The Daily Beast comments on that, and nine other high-profile divorces of the '00s. Read These Next Trump doesn't use pot, but he's mulling pot-friendly policy. Hegseth admires pastors with some eyebrow-raising thoughts on women. Ivanka and Jared are making headlines again. Nutritionists and regulators are rethinking orange juice. Report an error